The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.
A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC / Airi, A.; Atzori, C.; Bonino, F.; Damin, A.; Oien-ODegaard, S.; Aunan, E.; Bordiga, S.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 49:1(2019), pp. 12-16. [10.1039/c9dt04112e]
A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC
Airi A.Writing – Original Draft Preparation
;
2019
Abstract
The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.| File | Dimensione | Formato | |
|---|---|---|---|
|
DaltonTrans_2019.pdf
non disponibili
Tipologia:
final published article (publisher’s version)
Licenza:
Non Pubblico - Accesso privato/ristretto
Dimensione
2.64 MB
Formato
Adobe PDF
|
2.64 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
|
CeADC_DaltonT_post.pdf
Open Access dal 26/11/2020
Tipologia:
accepted manuscript (author’s post-print)
Licenza:
Pubblico - Tutti i diritti riservati
Dimensione
1.15 MB
Formato
Adobe PDF
|
1.15 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
